Brown University and University of Rhode Island Team Wins $6.17 Million DOE EPSCoR grant

Brown University and University of Rhode Island researchers led by principal investigator Pradeep R. Guduru, James R. Rice Associate Professor of Engineering at Brown, have won a three-year, $6.17 million grant from the Department of Energy (DOE) Experimental Program to Stimulate Competitive Research (EPSCoR). The project, “Fundamental Investigations of Mechanical and Chemical Degradation Mechanisms in Lithium Ion Battery Materials” will also involve Brown professors Allan Bower and Vivek Shenoy from the School of Engineering and Li-Qiong Wang from the Department of Chemistry; and Professors Brett Lucht, William Euler and Arijit Bose from the University of Rhode Island.

Electron microscopy images of the phase boundary between crystalline
silicon and amorphous lithiated silicon, revealing its atomic structure.
The sharp jumps in stress, composition and atomic structure across the
phase boundary play an important role in determining the mechanical
damage that results in silicon crystals during the initial charge cycle.

“This award represents a truly interdisciplinary research effort that brings together solid mechanics, chemistry and materials science,” said Guduru. “The research effort presents an opportunity for Brown and URI researchers to contribute to a technological area of national importance and forge strong collaborations with national labs and industry.”

“This new award contributes to the growing portfolio of engineering research at Brown in the energy and nanoscience fields,” said Dean Larry Larson. “These new fields are changing the way we live in thousands of different ways. Congratulations to all the faculty, post-docs, staff and students involved in these successful efforts.”

Electron microscopy images of the phase boundary between crystalline
silicon and amorphous lithiated silicon, revealing its atomic structure.
The sharp jumps in stress, composition and atomic structure across the
phase boundary play an important role in determining the mechanical
damage that results in silicon crystals during the initial charge cycle.

Despite the rapid advances in lithium ion battery (LIB) technology in recent years, major obstacles remain for vehicular applications of LIBs. It is widely recognized that further critical breakthroughs in the science and technology of lithium ion battery materials are necessary to develop the next generation of low-cost, long-life, higher energy density batteries for extended range electric vehicles.

The objective of the reserach funded under the DOE EPSCoR grant is to establish a comprehensive research program at Brown University and University of Rhode Island to develop fundamental and quantitative understanding of degradation mechanisms that limit the performance and cycle life of LIBs; and use the insights gained to help develop materials and architectures with significantly improved performance.

The research program encompasses critical challenges in the three major battery components: anodes, electrolytes and cathodes. Mechanical and chemical degradation of electrodes associated with large volume changes during charging and discharging is a critical factor that limits their capacity and lifetime. However, the degradation mechanisms are not well-understood quantitatively, which is a critical obstacle in developing the next generation of LIBs. The research team will address the fundamental issues of mechanical behavior & performance, controlling electrochemical side-reactions, formation and stability of solid-electrolyte interphase (SEI) layers. Through a combined experimental and computational approach, the team plans to develop the necessary quantitative understanding, which can help make battery materials design a well-controlled, principle-based process with predictable outcomes, in contrast to the largely trial and error based empirical approach being followed currently. The PIs will work with collaborators in national laboratories and battery industry in addressing the relevant problems of highest impact for developing the next generation of higher energy density battery systems.

Brown University Wins $6.25 Million MURI grant from Army Research Office

Brown and Cal State Northridge are teaming up on a $6.25 million Multi-University Research Initiative (MURI) grant from the Army Research Office (ARO) to study “Stress Controlled Catalysis via Engineering Nanostructures”. The five-year project will be led by principal investigator Bill Curtin, with collaborators Pradeep Guduru and Sharvan Kumar in the School of Engineering, Shouheng Sun in Chemistry and Engineering, and Gang Lu in Physics at Cal State Northridge. Four graduate students and six postdocs will join the faculty in executing the research.

Professor Bill Curtin '81

“This new award contributes to the growing portfolio of engineering research at Brown in the energy and nanosciences fields,” said Dean Larry Larson. “These new fields are changing the way we live in thousands of different ways. Congratulations to all the faculty, post-docs, staff and students involved in these successful efforts.”

The goal of the research is to demonstrate that macroscopic applied mechanical loading can be used to actively control and tune catalytic reactions through the use of innovative nanoscale material systems.


The challenge lies in obtaining stresses in the catalytic metal materials that are large enough to significantly influence the rates of selected chemical reactions in an overall catalytic process.

Associate Professor Pradeep Guduru

Professor Sharvan Kumar

Brown researchers will accomplish this by creating ultra-strong nanostructured materials in novel geometries where the mechanical load can be controlled and varied, also serving to isolate strain as the only experimental variable.

If the principle is demonstrated, then it may be possible to increase catalytic efficiencies by using time-varying stresses to actively control the reactions during operation, opening up the field of catalysis to an entirely new space of materials design.