Brown University and University of Rhode Island Team Wins $6.17 Million DOE EPSCoR grant

Brown University and University of Rhode Island researchers led by principal investigator Pradeep R. Guduru, James R. Rice Associate Professor of Engineering at Brown, have won a three-year, $6.17 million grant from the Department of Energy (DOE) Experimental Program to Stimulate Competitive Research (EPSCoR). The project, “Fundamental Investigations of Mechanical and Chemical Degradation Mechanisms in Lithium Ion Battery Materials” will also involve Brown professors Allan Bower and Vivek Shenoy from the School of Engineering and Li-Qiong Wang from the Department of Chemistry; and Professors Brett Lucht, William Euler and Arijit Bose from the University of Rhode Island.

Electron microscopy images of the phase boundary between crystalline
silicon and amorphous lithiated silicon, revealing its atomic structure.
The sharp jumps in stress, composition and atomic structure across the
phase boundary play an important role in determining the mechanical
damage that results in silicon crystals during the initial charge cycle.

“This award represents a truly interdisciplinary research effort that brings together solid mechanics, chemistry and materials science,” said Guduru. “The research effort presents an opportunity for Brown and URI researchers to contribute to a technological area of national importance and forge strong collaborations with national labs and industry.”

“This new award contributes to the growing portfolio of engineering research at Brown in the energy and nanoscience fields,” said Dean Larry Larson. “These new fields are changing the way we live in thousands of different ways. Congratulations to all the faculty, post-docs, staff and students involved in these successful efforts.”

Electron microscopy images of the phase boundary between crystalline
silicon and amorphous lithiated silicon, revealing its atomic structure.
The sharp jumps in stress, composition and atomic structure across the
phase boundary play an important role in determining the mechanical
damage that results in silicon crystals during the initial charge cycle.

Despite the rapid advances in lithium ion battery (LIB) technology in recent years, major obstacles remain for vehicular applications of LIBs. It is widely recognized that further critical breakthroughs in the science and technology of lithium ion battery materials are necessary to develop the next generation of low-cost, long-life, higher energy density batteries for extended range electric vehicles.

The objective of the reserach funded under the DOE EPSCoR grant is to establish a comprehensive research program at Brown University and University of Rhode Island to develop fundamental and quantitative understanding of degradation mechanisms that limit the performance and cycle life of LIBs; and use the insights gained to help develop materials and architectures with significantly improved performance.

The research program encompasses critical challenges in the three major battery components: anodes, electrolytes and cathodes. Mechanical and chemical degradation of electrodes associated with large volume changes during charging and discharging is a critical factor that limits their capacity and lifetime. However, the degradation mechanisms are not well-understood quantitatively, which is a critical obstacle in developing the next generation of LIBs. The research team will address the fundamental issues of mechanical behavior & performance, controlling electrochemical side-reactions, formation and stability of solid-electrolyte interphase (SEI) layers. Through a combined experimental and computational approach, the team plans to develop the necessary quantitative understanding, which can help make battery materials design a well-controlled, principle-based process with predictable outcomes, in contrast to the largely trial and error based empirical approach being followed currently. The PIs will work with collaborators in national laboratories and battery industry in addressing the relevant problems of highest impact for developing the next generation of higher energy density battery systems.

General Motors to Provide $2 Million to Brown to Continue Collaborative Research Laboratory on Computational Materials Science for Next 5 Years

Providence, RI - General Motors will provide $2 million in funding to Brown to continue the GM/Brown Collaborative Research Laboratory on Computational Materials Science for the next five years. The laboratory for computational materials research at Brown University is one of several collaborative research laboratories General Motors has established worldwide to accelerate the pace of innovation in strategic technology areas. The GM/Brown collaboration has existed for about the past ten years.

The goal of the laboratory is to develop computer simulations that predict the mechanical properties of materials used in automotive applications, and to use these simulations to help General Motors to develop materials with enhanced performance.  The computations are guided and verified by experiments.  Over the next five years, the laboratory will continue to focus on the development of lightweight materials, an increasingly important topic for all automotive subsystems because it is a key enabler for developing more energy efficient products.

"The CRL is a unique opportunity for Brown students and faculty to work with one of the best industrial research labs in the world," said Allan Bower, co-director of the CRL.  "By partnering with GM, we can make sure that the latest advances in computer simulation of material behavior are being used to help reduce vehicle weight and improve fuel economy."

Notable achievements of the laboratory include the development of multi-scale simulation methods to predict the influence of chemical composition on the rate sensitivity of aluminum alloys; improved modeling of the behavior of aluminum during forming and of the microstructure evolution in aluminum-silicon alloys; development and experimental validation of computer simulation methods to predict constitutive behavior and microstructure evolution in aluminum alloys; and the development of wear resistant diamond coatings.

At Brown, the lab is led by professor Allan Bower (co-director) and at General Motors, the co-director is Mark Verbrugge. Together, the two co-directors plan the work of the Collaborative Research Lab.

For further information, please see http://www.engin.brown.edu/facilities/GM_CRL

Professor Allan Bower publishes new book, Applied Mechanics of Solids

Professor Allan Bowers new book, Applied Mechanics of Solids, comes out today, October 1, 2009.

Applied Mechanics of Solids summarizes the physical laws, mathematical methods, and computer algorithms that are used to predict the response of materials and structures to mechanical or thermal loading.

Topics include: the mathematical descriptions of deformation and forces in solids; constitutive laws; analytical techniques and solutions to linear elastic and elastic-plastic boundary value problems; the use and theory of finite element analysis; fracture mechanics; and the theory of deformable rods, plates and shells.

Over 400 practice problems are provided on a companion web site, as well as demonstration finite element codes in MAPLE and MATLAB. The text is intended for advanced undergraduate or graduate students, as well as practicing engineers and scientists. It will be particularly useful to readers who wish to learn enough about solid mechanics to impress their teachers, colleagues, research advisors, or managers, but who would prefer not to study the subject in depth.

An electronic version of the text can be accessed at http://solidmechanics.org and its also available from Amazon.